TERAHERTZ TRANSMISSION SPECTRA OF CONDENSATES OF NITRO COMPOUNDS
https://doi.org/10.26583/vestnik.2025.3.8
EDN: TSQODE
Abstract
The work studied terahertz (THz) transmission spectra of hexogen (RDX, cyclotrimethylenetrinitramine) film experimentally and theoretically in the frequency region of the intense characteristic absorption band of RDX ~0.8 THz at different incidence angles (0˚ – 60˚) and polarization of the probing THz radiation. Registration of experimental THz transmission spectra of the RDX sample was carried out using a THz radio vision setup with spectral resolution. For mathematical modeling of the spectra, the method of characteristic matrices of the medium (transfer matrices) was used. It is shown that both in the experimental and in the theoretical THz transmission spectra of the RDX film for all studied incidence angles and polarizations of the probing THz radiation, the manifestation of the hexogen absorption band in the form of a local minimum in the frequency region of ~0.8 THz is clearly observed. The results of the work can be used in the development of terahertz systems designed for the spectral identification of substances in a condensed state.
About the Authors
E. R. ZhivagoRussian Federation
A. A. Plekhanov
Russian Federation
G. E. Kotkovskii
Russian Federation
I. L. Martynov
Russian Federation
S. V. Fadeev
Russian Federation
A. A. Chistyakov
Russian Federation
References
1. Konek C., Wilkinson J., Esenturk O., Heilweil E., Kemp M. Terahertz spectroscopy of explosives and simulants: RDX, PETN, sugar, and L-tartaric acid. Terahertz Physics, Devices, and Systems III: Advanced Applications in Industry and Defense. – SPIE, 2009, vol. 7311, pp. 121-127. doi:10.1117/12.817913
2. Chen J., Chen, Y., Zhao, H., Bastiaans, G. J., & Zhang, X. C. Absorption coefficients of selected explosives and related compounds in the range of 0.1–2.8 THz. Optics express, 2007, vol. 15, no. 19, pp. 12060-12067. doi:10.1364/OE.15.012060
3. Ornik J., Knoth D., Koch M., Keck C.M. Terahertz-spectroscopy for non-destructive determination of crystallinity of L-tartaric acid in smartFilms® and tablets made from paper. International journal of pharmaceutics, 2020, vol.581, pp.119253. doi:10.1016/j.ijpharm.2020.119253
4. Yoo B.H., Kang S. B., Kwak M. H., Kim S. I., Kim T.Y., Ryu H.C., Jun D. S., Paek M. C., Kang K. Y., Chung D.C. Guided Wave THz Spectroscopy of Explosive Materials. Journal of the Korean Institute of Electromagnetic and Science, 2011, vol.11, no.1, pp.42-50. doi:10.5515/JKIEES.2011.11.1.042
5. Born M., Wolf E. Osnovy optiki [Fundamentals of Optics]. Moscow, Nauka Publ., 1973. 719 p. (in Russian)
6. Plekhanov A. A., Akmalov A. E., Kotkovskii G. E., Kozlovskii K. I., Kuzishchin Y. A., Martynov I. L., Maksimov E. M., Osipov E. V., Chistyakov A. A. Study of terahertz reflection spectra of optically thin RDX samples by terahertz imaging with spectral resolution. Optical Engineering, 2023, vol.62, no. 3, pp. 034109-034109. doi:10.1117/1.OE.62.3.034109
7. Berry C. W., Jarrahi M. Broadband terahertz polarizing beam splitter on a polymer substrate. Journal of Infrared, Millimeter, and Terahertz Waves, 2012, vol.33, pp. 127-130. doi:10.1007/s10762-011-9858-6
8. Efimova A.I., Zaitsev V.B., Boldyrev N.Yu., Kashkarov P.K. Infrakrasnaya furye-spektrometriya [Infrared Fourier spectrometry] Moscow, Phys. Department of Moscow State Univ.Publ., 2008, 133 p. (in Russian)
9. Zhang Q. The refractive angle of light propagation at absorbing media interface. Optik, 2015, vol. 126, no. 23, pp. 4387-4391. doi:10.1016/j.ijleo.2015.08.148
10. Smith D. R., Loewenstein E. V. Optical constants of far infrared materials. 3: plastics. Applied Optics, 1975, vol. 14, no. 6, pp. 1335-1341. doi:10.1364/AO.14.001335
11. Baker C., Lo T., Tribe W. R., Cole B.E., Hogbin M. R., Kemp M. C Detection of concealed explosives at a distance using terahertz technology. Proceedings of the IEEE, 2007, vol. 95, no. 8, pp. 1559-1565. doi:10.1109/JPROC.2007.900329
Supplementary files
Review
For citations:
Zhivago E.R., Plekhanov A.A., Kotkovskii G.E., Martynov I.L., Fadeev S.V., Chistyakov A.A. TERAHERTZ TRANSMISSION SPECTRA OF CONDENSATES OF NITRO COMPOUNDS. Vestnik natsional'nogo issledovatel'skogo yadernogo universiteta "MIFI". 2025;14(3):256-263. (In Russ.) https://doi.org/10.26583/vestnik.2025.3.8. EDN: TSQODE